{"id":385121,"date":"2024-10-20T03:29:11","date_gmt":"2024-10-20T03:29:11","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bs-en-iec-62321-3-32021\/"},"modified":"2024-10-26T06:19:07","modified_gmt":"2024-10-26T06:19:07","slug":"bs-en-iec-62321-3-32021","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bs-en-iec-62321-3-32021\/","title":{"rendered":"BS EN IEC 62321-3-3:2021"},"content":{"rendered":"

This part of IEC 62321 specifies the screening analysis of polybrominated biphenyls (PBBs), polybrominated diphenyl ethers (PBDEs), di-isobutyl phthalate (DIBP), di-n-butyl phthalate (DBP), benzylbutyl phthalate (BBP), di-(2-ethylhexyl) phthalate (DEHP), di-n-octyl phthalate (DNOP), di-isononyl phthalate (DINP), and di-isodecyl phthalate (DIDP) in polymers of electrotechnical products using the analytical technique of gas chromatography-mass spectrometry using a pyrolyser\/thermal desorption accessory (Py\/TD-GC-MS). This test method has been evaluated through the analysis of PP (polypropylene), PS (polystyrene), and PVC (polyvinyl chloride) materials containing deca-BDE between 100 mg\/kg and 1 000 mg\/kg and individual phthalates between 100 mg\/kg to 4 000 mg\/kg as depicted in Annex J. Use of the methods described in this document for other polymer types, PBBs (mono-deca), PBDEs (mono-deca) and phthalates or concentration ranges other than those specified above has not been specifically evaluated. This document has the status of a horizontal standard in accordance with IEC Guide 108 [1]1.<\/p>\n

PDF Catalog<\/h4>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
PDF Pages<\/th>\nPDF Title<\/th>\n<\/tr>\n
2<\/td>\nundefined <\/td>\n<\/tr>\n
4<\/td>\nEuropean foreword
Endorsement notice <\/td>\n<\/tr>\n
5<\/td>\nEnglish
CONTENTS <\/td>\n<\/tr>\n
7<\/td>\nFOREWORD <\/td>\n<\/tr>\n
9<\/td>\nINTRODUCTION <\/td>\n<\/tr>\n
10<\/td>\n1 Scope
2 Normative references
3 Terms, definitions and abbreviated terms
3.1 Terms and definitions <\/td>\n<\/tr>\n
12<\/td>\n3.2 Abbreviated terms <\/td>\n<\/tr>\n
13<\/td>\n4 Principle
4.1 Overview <\/td>\n<\/tr>\n
14<\/td>\n4.2 Principle of test
5 Reagents and materials <\/td>\n<\/tr>\n
15<\/td>\n6 Apparatus
7 Sampling
8 Procedure
8.1 General instructions for the analysis <\/td>\n<\/tr>\n
16<\/td>\n8.2 Sample preparation
8.2.1 General
8.2.2 Polymer sample
8.2.3 Stock solution or polymer reference material
8.3 Instrumental parameters <\/td>\n<\/tr>\n
17<\/td>\nTables
Table 1 \u2013 Measurement conditions of Py\/TD-GC-MS <\/td>\n<\/tr>\n
18<\/td>\n8.4 Calibration
8.4.1 General
8.4.2 Determination of RRFs <\/td>\n<\/tr>\n
19<\/td>\n9 Calculation of PBBs, PBDEs and phthalates concentration
9.1 General <\/td>\n<\/tr>\n
20<\/td>\n9.2 Determination of RF of DEHP
9.3 Calculation
9.3.1 Calculation of RF
9.3.2 Calculation of concentration <\/td>\n<\/tr>\n
21<\/td>\n10 Precision
10.1 Screening judgement
Table 2 \u2013 IIS3-3 Screening and threshold judgement <\/td>\n<\/tr>\n
23<\/td>\n10.2 Repeatability and reproducibility
Table 3 \u2013 IIS3-3 Repeatability and reproducibility (phthalate) <\/td>\n<\/tr>\n
24<\/td>\nTable 4 \u2013 IIS3-3 Repeatability and reproducibility (PBB) <\/td>\n<\/tr>\n
25<\/td>\nTable 5 \u2013 IIS3-3 Repeatability and reproducibility (PBDE) <\/td>\n<\/tr>\n
26<\/td>\n11 Quality assurance and control
11.1 General
11.2 Quality control
11.2.1 Sensitivity test
11.2.2 Blank test <\/td>\n<\/tr>\n
27<\/td>\n11.2.3 System stability test
11.2.4 Degradation test
11.2.5 RRF test <\/td>\n<\/tr>\n
28<\/td>\n11.3 Method detection limit (MDL) and limit of quantification (LOQ)
12 Test report <\/td>\n<\/tr>\n
29<\/td>\nAnnex A (informative)Flow chart of screening and verification test method
Figures
Figure A.1 \u2013 Flow chart for screening step and verificationtest step for PBDEs, PBBs and phthalates <\/td>\n<\/tr>\n
30<\/td>\nTable A.1 \u2013 Screening methods for phthalate esters,PBBs and PBDEs in the IEC 62321 series <\/td>\n<\/tr>\n
31<\/td>\nAnnex B (informative)Principle of Py\/TD-GC-MS instruments
Figure B.1 \u2013 Example of Py\/TD-GC-MS instrument <\/td>\n<\/tr>\n
32<\/td>\nAnnex C (informative)Other test methods
Table C.1 \u2013 Other test methods <\/td>\n<\/tr>\n
33<\/td>\nAnnex D (informative)Commercially available reference solutions and materials
D.1 Reference solution
Table D.1 \u2013 Example list of commercially availablereference solutions of PBBs and PBDEs <\/td>\n<\/tr>\n
34<\/td>\nD.2 Polymer reference materials
Table D.2 \u2013 Example list of commercially available reference solutions of phthalates
Table D.3 \u2013 Example list of commercially available reference materials of PBBs, PBDEs and PS considered suitable for Py\/TD-GC-MS <\/td>\n<\/tr>\n
35<\/td>\nFigure D.1 \u2013 Sample preparation of reference materials
Table D.4 \u2013 Example list of commercially available reference materialsof phthalates considered suitable for Py\/TD-GC-MS <\/td>\n<\/tr>\n
36<\/td>\nAnnex E (informative)Sampling procedure
E.1 Sample preparation using cutting tools
E.2 Sample preparation using cryogenic grinding mill
E.3 Accurate weighing of sample
E.4 Method of sample injection
Table E.1 \u2013 Example of variation of weighting samples <\/td>\n<\/tr>\n
37<\/td>\nAnnex F (informative)Verification of the EGA thermal desorption zone
Figure F.1 \u2013 Example of EGA thermogram of a PVC sample containing phthalates <\/td>\n<\/tr>\n
38<\/td>\nFigure F.2 \u2013 Example of EGA thermogram of a polystyrene sample containing PBDEs <\/td>\n<\/tr>\n
39<\/td>\nAnnex G (informative)Example of chromatograms
Figure G.1 \u2013 Total ion current chromatogram of 0,1 \u00b5g of PBBs, PBDEsand phthalates mixture by Py\/TD-GC-MS <\/td>\n<\/tr>\n
40<\/td>\nAnnex H (informative)Examples of RRFs
Table H.1 \u2013 RRFs of analytes <\/td>\n<\/tr>\n
41<\/td>\nAnnex I (informative)Sample analysis sequence
Table I.1 \u2013 Sample analysis sequence for Py\/TD-GC-MS analysis <\/td>\n<\/tr>\n
42<\/td>\nAnnex J (informative)Results of international inter-laboratory study 3-3
Table J.1 \u2013 Statistical data for phthalates <\/td>\n<\/tr>\n
43<\/td>\nTable J.2 \u2013 Statistical data for polybrominated biphenyls <\/td>\n<\/tr>\n
44<\/td>\nTable J.3 \u2013 Statistical data for polybrominated diphenyl ethers <\/td>\n<\/tr>\n
45<\/td>\nBibliography <\/td>\n<\/tr>\n
47<\/td>\nFran\u00e7ais
SOMMAIRE <\/td>\n<\/tr>\n
50<\/td>\nAVANT-PROPOS <\/td>\n<\/tr>\n
52<\/td>\nINTRODUCTION <\/td>\n<\/tr>\n
53<\/td>\n1 Domaine d’application
2 R\u00e9f\u00e9rences normatives
3 Termes, d\u00e9finitions et termes abr\u00e9g\u00e9s
3.1 Termes et d\u00e9finitions <\/td>\n<\/tr>\n
55<\/td>\n3.2 Termes abr\u00e9g\u00e9s <\/td>\n<\/tr>\n
56<\/td>\n4 Principe
4.1 Pr\u00e9sentation
4.2 Principe de l\u2019essai <\/td>\n<\/tr>\n
57<\/td>\n5 R\u00e9actifs et mat\u00e9riaux <\/td>\n<\/tr>\n
58<\/td>\n6 Appareils
7 \u00c9chantillonnage
8 Proc\u00e9dure
8.1 Instructions g\u00e9n\u00e9rales pour l\u2019analyse <\/td>\n<\/tr>\n
59<\/td>\n8.2 Pr\u00e9paration des \u00e9chantillons
8.2.1 G\u00e9n\u00e9ralit\u00e9s
8.2.2 \u00c9chantillon de polym\u00e8re
8.2.3 Solution m\u00e8re ou mat\u00e9riau polym\u00e8re de r\u00e9f\u00e9rence
8.3 Param\u00e8tres instrumentaux <\/td>\n<\/tr>\n
60<\/td>\nTableaux
Tableau 1 \u2013 Conditions de mesure par Py\/TD-GC-MS <\/td>\n<\/tr>\n
61<\/td>\n8.4 \u00c9talonnage
8.4.1 G\u00e9n\u00e9ralit\u00e9s
8.4.2 D\u00e9termination des RRF <\/td>\n<\/tr>\n
63<\/td>\n9 Calcul de la concentration des PBB, des PBDE et des phtalates
9.1 G\u00e9n\u00e9ralit\u00e9s
9.2 D\u00e9termination du RF de DEHP
9.3 Calcul
9.3.1 Calcul du RF <\/td>\n<\/tr>\n
64<\/td>\n9.3.2 Calcul de la concentration
10 Fid\u00e9lit\u00e9
10.1 Estimation de la d\u00e9tection <\/td>\n<\/tr>\n
65<\/td>\nTableau 2 \u2013 Estimation de la d\u00e9tection et du seuil IIS3-3 <\/td>\n<\/tr>\n
66<\/td>\n10.2 R\u00e9p\u00e9tabilit\u00e9 et reproductibilit\u00e9 <\/td>\n<\/tr>\n
67<\/td>\nTableau 3 \u2013 R\u00e9p\u00e9tabilit\u00e9 et reproductibilit\u00e9 IIS3-3 (phtalate) <\/td>\n<\/tr>\n
68<\/td>\nTableau 4 \u2013 R\u00e9p\u00e9tabilit\u00e9 et reproductibilit\u00e9 IIS3-3 (PBB) <\/td>\n<\/tr>\n
69<\/td>\nTableau 5 \u2013 R\u00e9p\u00e9tabilit\u00e9 et reproductibilit\u00e9 IIS3-3 (PBDE) <\/td>\n<\/tr>\n
70<\/td>\n11 Assurance qualit\u00e9 et contr\u00f4le de la qualit\u00e9
11.1 G\u00e9n\u00e9ralit\u00e9s
11.2 Contr\u00f4le de la qualit\u00e9
11.2.1 Essai de sensibilit\u00e9
11.2.2 Essai t\u00e9moin <\/td>\n<\/tr>\n
71<\/td>\n11.2.3 Essai de stabilit\u00e9 du syst\u00e8me
11.2.4 Essai de d\u00e9gradation <\/td>\n<\/tr>\n
72<\/td>\n11.2.5 Essai de RRF
11.3 Limite de d\u00e9tection de la m\u00e9thode (MDL) et limite de quantification (LOQ) <\/td>\n<\/tr>\n
73<\/td>\n12 Rapport d’essai <\/td>\n<\/tr>\n
74<\/td>\nAnnexe A (informative)Organigramme de la m\u00e9thode d\u2019essai de d\u00e9tection et de v\u00e9rification
Figures
Figure A.1 \u2013 Organigramme de l\u2019\u00e9tape d\u2019essai de d\u00e9tection et de l\u2019\u00e9tape d\u2019essai de v\u00e9rification des PBDE, PBB et phtalates <\/td>\n<\/tr>\n
75<\/td>\nTableau A.1 \u2013 M\u00e9thodes de d\u00e9tection des esters de phtalates, des PBB et des PBDE de la s\u00e9rie IEC 62321 <\/td>\n<\/tr>\n
76<\/td>\nAnnexe B (informative)Principe des instruments Py\/TD-GC-MS
Figure B.1 \u2013 Exemple d\u2019instrument Py\/TD-GC-MS <\/td>\n<\/tr>\n
77<\/td>\nAnnexe C (informative)Autres m\u00e9thodes d\u2019essai
Tableau C.1 \u2013 Autres m\u00e9thodes d\u2019essai <\/td>\n<\/tr>\n
78<\/td>\nAnnexe D (informative)Solutions et mat\u00e9riaux de r\u00e9f\u00e9rence disponibles dans le commerce
D.1 Solution de r\u00e9f\u00e9rence
Tableau D.1 \u2013 Exemple de liste de solutions de r\u00e9f\u00e9rence de PBB et de PBDE disponibles dans le commerce <\/td>\n<\/tr>\n
79<\/td>\nD.2 Mat\u00e9riaux polym\u00e8res de r\u00e9f\u00e9rence
Tableau D.2 \u2013 Exemple de liste de solutions de r\u00e9f\u00e9rence de phtalates disponibles dans le commerce
Tableau D.3 \u2013 Exemple de liste de mat\u00e9riaux de r\u00e9f\u00e9rence de PBB, PBDE et de PS du commerce consid\u00e9r\u00e9s comme appropri\u00e9s pour l\u2019analyse Py\/TD-GC-MS <\/td>\n<\/tr>\n
80<\/td>\nFigure D.1 \u2013 Pr\u00e9paration d’\u00e9chantillon de mat\u00e9riaux de r\u00e9f\u00e9rence
Tableau D.4 \u2013 Exemple de liste de mat\u00e9riaux de r\u00e9f\u00e9rence de phtalate du commerce consid\u00e9r\u00e9s comme appropri\u00e9s pour l\u2019analyse Py\/TD-GC-MS <\/td>\n<\/tr>\n
81<\/td>\nAnnexe E (informative)Proc\u00e9dure d\u2019\u00e9chantillonnage
E.1 Pr\u00e9paration des \u00e9chantillons \u00e0 l\u2019aide d\u2019outils de coupe
E.2 Pr\u00e9paration des \u00e9chantillons \u00e0 l\u2019aide d\u2019un broyeur cryog\u00e9nique
E.3 Exactitude de pes\u00e9e de l\u2019\u00e9chantillon
E.4 M\u00e9thode d\u2019injection de l\u2019\u00e9chantillon
Tableau E.1 \u2013 Exemple de variation du poids des \u00e9chantillons de pes\u00e9e <\/td>\n<\/tr>\n
82<\/td>\nAnnexe F (informative)V\u00e9rification de la zone de thermod\u00e9sorption par AGE
Figure F.1 \u2013 Exemple de thermogramme d\u2019AGE d\u2019un \u00e9chantillon de PVC contenant des phtalates <\/td>\n<\/tr>\n
83<\/td>\nFigure F.2 \u2013 Exemple de thermogramme d\u2019AGE d\u2019un \u00e9chantillon de polystyr\u00e8ne contenant des PBDE <\/td>\n<\/tr>\n
84<\/td>\nAnnexe G (informative)Exemple de chromatogrammes
Figure G.1 \u2013 Chromatogramme du courant ionique total de 0,1 \u00b5g de m\u00e9lange PBB\/PBDE et phtalates par analyse Py\/TD-GC-MS <\/td>\n<\/tr>\n
85<\/td>\nAnnexe H (informative)Exemple de r\u00e9sultats de RRF obtenus
Tableau H .1 \u2013 RRF des analytes <\/td>\n<\/tr>\n
86<\/td>\nAnnexe I (informative)S\u00e9quence d\u2019analyse d\u2019\u00e9chantillon
Tableau I.1 \u2013 S\u00e9quence d\u2019analyse d\u2019\u00e9chantillon pour l\u2019analyse Py\/TD-GC-MS <\/td>\n<\/tr>\n
87<\/td>\nAnnexe J (informative)R\u00e9sultats de l’\u00e9tude internationale interlaboratoires 3-3
Tableau J.1 \u2013 Donn\u00e9es statistiques pour les phtalates <\/td>\n<\/tr>\n
88<\/td>\nTableau J.2 \u2013 Donn\u00e9es statistiques pour les diph\u00e9nyles polybrom\u00e9s <\/td>\n<\/tr>\n
89<\/td>\nTableau J.3 \u2013 Donn\u00e9es statistiques pour les diph\u00e9nyl\u00e9thers polybrom\u00e9s <\/td>\n<\/tr>\n
90<\/td>\nBibliographie <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":"

Determination of certain substances in electrotechnical products – Screening. Polybrominated biphenyls, polybrominated diphenyl ethers and phthalates in polymers by gas chromatography-mass spectrometry using a pyrolyser\/thermal desorption accessory (Py\/TD-GC-MS)<\/b><\/p>\n\n\n\n\n
Published By<\/td>\nPublication Date<\/td>\nNumber of Pages<\/td>\n<\/tr>\n
BSI<\/b><\/a><\/td>\n2021<\/td>\n92<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"featured_media":385127,"template":"","meta":{"rank_math_lock_modified_date":false,"ep_exclude_from_search":false},"product_cat":[183,2641],"product_tag":[],"class_list":{"0":"post-385121","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-13-020-01","7":"product_cat-bsi","9":"first","10":"instock","11":"sold-individually","12":"shipping-taxable","13":"purchasable","14":"product-type-simple"},"_links":{"self":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product\/385121","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/types\/product"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media\/385127"}],"wp:attachment":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media?parent=385121"}],"wp:term":[{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_cat?post=385121"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_tag?post=385121"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}